The two presidents had held talks and met with business leaders from both countries before facing the media at the Great Hall of the People in central Beijing.
The travel rush started from Monday and will last till March 1, during which railway trips are expected to hit 413 million in total, up 8.3 percent from a year ago.
The two foreign ministers also exchanged opinions on regional and international issues including the Korean Peninsula issue. They vowed to jointly safeguard the free trade system, promote regional economic integration and build an open world economy.
The travel agency said that about 30 percent of reservations on its platform were for trips to Thailand and Japan.
The trip route of the 165-tourist group, organized by China Youth Tourism Service (CYTS), one of the biggest tour operators in China, covers Tunisia, Morocco and Algeria.
The train is hauling auto parts, electronic machinery and equipment, valves and clothing made in Jilin province or places in northern China, and will pass through Russia, Belarus, Poland, Germany and Belgium before it arrives at the destination.
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The training network builds on Alibaba's Global e-commerce Talent program, which has so far trained nearly 7,000 students and about 2,000 SME owners, covering 10 countries around the globe, according to figures provided by company.
The transnational index of the country's top 100 multinationals, an index measuring the global operation of firms based on their overseas assets, revenues and employees, rose for a sixth consecutive year to 16.1 percent, up 0.14 percentage points from a year ago, according to the confederation and association.
The traditional way to eat them is with your fingers, dipping them in hollandaise sauce.
The two sides will work together to address a broad range of geopolitical and economic challenges, the White House said in a statement.